Freeze‐Thawed Nafion‐Poly(vinyl alcohol) Self‐healing Membranes for Direct Methanol Fuel Cells

نویسندگان

چکیده

Self-healing proton-exchange membranes (PEMs) made of poly(vinyl alcohol) (PVA) and Nafion were synthesized using the freeze-thaw method. Since PVA is more selective towards water than methanol, blend membrane successfully reduced methanol permeability improved selectivity compared to recast membrane. The addition also helped self-heal by promoting formation hydrogen bonds. In contrast pristine Nafion, which exhibited even severe crossover after being damaged before, Nafion-PVA underwent a self-healing process regained much its barrier function. These advantageous characteristics suggest potential use in direct fuel cells (DMFCs).

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ژورنال

عنوان ژورنال: Chemical Engineering & Technology

سال: 2023

ISSN: ['0930-7516', '1521-4125']

DOI: https://doi.org/10.1002/ceat.202300099